The success of the University of Kentucky Center for Applied Energy Research’s seed grant program was on full display Wednesday, as UK CAER investigators presented early-stage research projects to fellow CAER colleagues.
CAER’s seed grant program was created to bridge the divide between internal creative ideas and large government grants and/or industrial funding, with the objective being to develop a process of converting new research concepts into competitive proposals.
The success of the program can best be illustrated by the results. Since January 2013, CAER has invested $430,000 into seed projects. Those same projects have generated more than $940,000 in external funding and seven published papers. In fact, of the five external proposals submitted on behalf of seed projects, all five have received funding.
“The results are pretty obvious,” said Andrews. “We knew that CAER investigators had some novel concepts that simply needed some start-up funding to get off the ground, and this program allowed us to fund those innovative, early-stage ideas. It is exciting to see these concepts grow and receive support from external agencies, as they move into the next phase of discovery.”
On Wednesday, the following projects were spotlighted during the seed grant poster presentations event at CAER. These projects were all funded in 2015.
- Michael Wilson, Stephanie Kesner, and Daniel Mohler - Integrating Algal Based CO2 Utilization and Waste Water Treatment
Photosynthetically grown microalgae have the potential to recycle many waste streams, including CO2 emissions and municipal, agricultural, or industrial waste water. Samples were obtained from the Lexington Fayette Urban County Government Division of Water Quality to evaluate the suitability of waste water as a nutrient source and habitat to culture microalgae. Ion chromatography was used to evaluate various waste water streams from the Town Branch wastewater treatment plant and to track nutrient uptake of algae cultures. Although the waste streams sampled did not contain high values of usable nutrients, it’s suitability as an industrial scale habitat was verified.
- Tristana Duvallet and Anne Oberlink - Sulfate-Activated Class C Fly Ash Based Cements
Recent research in the Environmental and Coal Technologies (ECT) group has determined that Wyodak coal source Class C fly ash can be activated through a sulfation mechanism with anhydrite to produce the fly ash equivalent of a “super-sulfated cement.” This constitutes a discovery that is of significance. Concretes and mortars produced with high levels of coal combustion products (CCPs) or supplemental cementitious materials (SCMs), such as fly ash or slag, in place of Portland cement can develop strength by the activation of the alumina and silica phases of the materials using strong alkalis (i.e. alkali activation, aka “geopolymer”). The alkali that is used as the activator is typically sodium or potassium silicate in combination with sodium or potassium hydroxide, and various alkalis, e.g. borates, citrates, sulfonates, etc. Drawbacks to this approach include: erratic setting, either lack of, or very slow setting or flash setting; slow strength development that may require curing at elevated temperatures; rheological problems with the concrete or mortars themselves, i.e. they become “sticky”; worker safety issues since high levels of sodium hydroxide exposure are dangerous; and long-term issues with surface efflorescence. Sulfation activation was thought to be a phenomenon restricted to ground granulated blast furnace slag (GGBFS) cement. The observation that a supersulfated cement can be based entirely on Class C fly ash instead of GGBFS, overcoming the drawbacks of alkali activation, has the potential to lead to a new generation of low energy, low CO2 concretes and mortars.
- Robert C. Pace - Biomass Fractionation via a Semi-continuous Method: Lignin Extraction with Ionic Liquids
Ionic Liquids (ILs) are highly adaptable organic salts which are liquid at room temperature. As a consequence of these properties, ILs are enormously effective in the dissolution of lignocellulosic biomass. Given the tremendous interest in the production of renewable fuels and chemicals from lignocellulose, these solvents present a novel pathway toward the fractionation of lignocellulose into its three primary components; cellulose, hemicellulose and lignin. Fractionation of these compounds is necessary for the use of the whole of the biomass, a requirement for cost-effective production from these feedstocks. To date, nearly all biomass fractionation using ILs has been conducted in batch processes. Since continuous extraction systems are often more energy efficient and economical, this project will set out to construct a semi-continuous extraction system which is capable of overcoming the high viscosities of ILs. In order to discern the effects of various functionalities as well as the impact of cation/anion effects, five ILs will be examined as extraction solvents. The products of these fractionation experiments will also be analyzed by various means, including thermogravimetric analysis, pyrolysis-GCMS and gel permeation chromatography. This work will lead not only to valuable data which can be utilized in publications and future grant proposals, but will also generate an apparatus which is capable of producing unique IL extracted biomaterials which could be sold as commodity products and utilized by students in their own research projects within the BEC group.
- Chad Risko, Adam Rigby and Karl Thorley, - A Computational, Shape-Based Approach to Crystal Engineering
Organic semiconductors (OSC) are experiencing rapid application growth in consumer electronics, with OSC poised to serve a key role in next generation flexible, conformable, and wearable electronics. However, the reliance on largely Edisonian discovery processes results in significant development and production costs – in terms of personnel, materials, characterization equipment, and time – for new, molecular-based OSCs. High-performance computing, when combined with the tool set and know-how of the synthetic chemist, offers a means to overcome many of these costs. Through a joint collaboration between the Anthony and Risko groups, we are developing an innovative computational approach to determine how the interplay between of molecular shape and explicit chemical functionality drive molecular packing in the solid state, a key determinant of OSC performance. The development of the computational platform will allow for rapid approximations of molecular packing structures, with relevant solutions arriving within days and weeks rather than the months required for synthesis and characterization, along with the ability to screen varied and unusual molecular designs that may otherwise go untried. Through the course of the work, the research team has improved understanding as to how solid-state molecular conformations impact the intermolecular electronic coupling, a key parameter directing charge-carrier transport in these materials. The project introduced a new concept, the disordermer, into the crystal engineering lexicon, and shown how changes in chemical composition can be manifest on crystalline order and the resulting charge-carrier transport properties. The lab has also made considerable headway in terms of developing a model that reveals how adjustments in the overall molecular shape and volume direct solid-state packing. The work has resulted in three peer-reviewed publications (two published and one submitted) and one proposal submitted to the National Science Foundation.
- Rafael Franca and John Craddock - A New Approach to Novel Zeolite Hollow Fiber Membranes for Dewatering and Enrichment Separations in CO2 Capture Process
Zeolite membrane-based technology for dewatering of aqueous amine-based CO2 sorbents, has the capability to significantly decrease the energy required for CO2 capture from coal-fired power plants. Membrane enabled dewatering of CO2 saturated amine solvent, reduces the thermal energy required by the stripper during solvent regeneration by commensurately reducing the volume of water to be heated. The hollow fiber membrane (HFM) geometry provides high surface area to volume and high permselectivity. These membranes have the potential to increase selectivity and flux in membrane-based dewatering processes when compared to conventional tubular membranes. In this work, we introduced the preparation of a novel, polymer-assisted processing of a Y Zeolite HFM support. The preparation method proposed is based on air-gap solution spinning of a polymer (polyethersulfone (PES)) solution containing highly dispersed mullite particles, followed by thermal treatment to pyrolize the polymer and sinter the mullite particles into an HFM form. It is expected that this new design (HFM) would greatly increase flux and selectivity of Y zeolite membranes for the dewatering of carbon-loaded amine solvents. Preliminary results indicated that mullite based hollow fiber supports did not present enough mechanical resistance after the sintering process. Zeolite Y crystals have been successfully grown on the outside surface of PES hollow fiber supports, however some level of degradation was observed when the support was exposed to the carbon loaded amine solvent. It is not clear if the degradation process affects the porosity of the PES hollow fiber support. Further tests will be conducted with PES hollow fibers to analyze the viability of using PES as a support for Y-zeolite hollow fibers.
- Christopher Swartz, "Hybrid Redox Flow Battery for Stationary Energy Storage Applications
The capability to store electricity is on track to become an integral component of the future electrical grid. Emerging technologies found in the grid storage portfolio include pumped hydro energy storage, compressed air energy storage, thermal and flywheel energy storage, and various electrochemical energy storage options, including redox flow batteries. Redox flow batteries share many similarities with fuel cells, and are rechargeable, modular battery systems where energy storage and power performance can be decoupled from one another due to the battery architecture. The all-vanadium redox flow battery represents the current state-of-the-art in flow battery technology, and numerous demonstration units have been installed worldwide, ranging from kW, kWh to MW, MWh capabilities. The relatively high cost of these systems has prevented widespread adoption of flow battery technology, and new flow battery systems featuring lower cost chemistries and ion exchange membranes (when compared to vanadium and Nafion®, respectively) remain highly attractive candidates to move flow batteries along on a forward trajectory to the commercial marketplace. The Electrochemical Power Sources Group proposes to develop a low-cost hybrid redox flow battery as an alternative to the all-vanadium system, based on aqueous iron and zinc electrochemistry. The cathode will feature plating and stripping of Zn metal during cell charge and discharge. The anode will feature the Fe2+/Fe3+ redox couple, with the addition of various ligands or chelating agents which will bind to iron, and lead to higher operating cell voltage and energy density.
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